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光电子能谱解析离子液体结构性能
内容简介
本书从光电子能谱角度，以揭示结构与性能间相互关系为目标，对离子液体进行了系统详细的阐述。同时对离子液体中的催化剂体系进行了初步介绍。本书共6章，包括离子液体主要物理化学性质简介，离子液体合成，X-射线光电子能谱简介，以及从光电子能谱角度研究纯离子液体体系和离子液体中催化剂体系等内容。本书根据高等学校工科学科发展的需要，注重理论知识的传授，同时强调实际应用。本书可供高等学校材料类、化学类或其他相关专业使用，也可用做有关技术人员的参考用书。读者通过本书的学习，能够掌握光电子能谱技术和离子液体领域的科学研究，有助于对现代材料测试技术以及催化化学、摩擦学、润滑技术等相关课程的学习。
章节目录
封面
书名页
版权页
Preface
前言
目录
Chapter 1 Ionic Liquids
1.1 Ionic liquids
1.1.1 Definition
1.1.2 A brief history of ionic liquids
1.2 Properties of ionic liquids
1.2.1 Why are ionic liquids liquid?
1.2.2 Viscosity
1.2.3 Low volatility
1.2.4 Conductivity
1.2.5 Solvation properties
1.3 Synthesis of ionic liquids
1.3.1 Materials
1.3.2 Instrumentation
1.3.3 Imidazolium-based ionic liquids
1.3.4 Pyrrolidinium-based ionic liquids
1.3.5 Pyridinium-based ionic liquids
1.4 Dissolution of metal catalysts in ionic liquids
1.4.1 The addition of phosphine ligands
1.4.2 The formation of phosphineimidazolylidene palladium complexes
1.5 Ionic liquids analysed in this book
1.6 Catalysis in ionic liquids
References
Chapter 2 X-ray Photoelectron Spectroscopy
2.1 X-ray photoelectron spectroscopy
2.1.1 Principle
2.1.2 Experimental set-up
2.1.3 Vacuum environment
2.1.4 Charge neutralisation
2.1.5 Data interpretation
2.2 XPS experiment
2.2.1 Instrument
2.2.2 Sample preparation and transfer
2.2.3 Information depth
2.2.4 Data processing
2.2.5 XP Spectrum
2.2.6 XPS analysis
2.2.7 Charge correction
2.2.8 Auger Parameter
2.3 XPS of ionic liquids
References
Chapter 3 XPS of Pure Ionic Liquids and Ionic Liquid Mixtures
3.1 Introduction
3.2 Varying the cation
3.2.1 Imidazolium-based ionic liquids
3.2.2 Pyrrolidinium-based ionic liquids
3.2.3 Pyridinium-based ionic liquids
3.2.4 Comparison of imidazolium, pyrrolidinium and pyridinium-based ionic liquids
3.3 Varying the anion
3.3.1 Acetate-based imidazolium ionic liquids
3.3.2 Effect of the anion on the cation
3.4 Ionic liquid mixture
3.4.1 Imidazolium-based ionic liquid mixture
3.4.2 Pyrrolidinium-based ionic liquid mixture
3.4.3 Pyridinium-based ionic liquid mixture
3.5 Conclusions
References
Chapter 4 XPS of Solute-solvent Interaction in Ionic Liquids
4.1 Introduction
4.2 Formation of a phosphineimidazolylidene palladium complex
4.3 Pd as a probe of solute-solvent interactions
4.4 Selection of anions: correlation of binding energy to established metrics
4.5 Can the solvent environment be tuned?
4.6 Can anion basicity impact on the reaction rate?
4.6.1 Suzuki cross coupling reaction
4.6.2 Correlation of binding energy with reaction rate
4.6.3 The catalytic activity of the palladium centre in ionic liquid mixture
4.7 Conclusions
References
Chapter 5 XPS of Metal-ligand Interaction in Ionic Liquids
5.1 Introduction
5.2 Detection of the rhodium centre in solution
5.3 Formation of the mono-phosphine rhodium complex
5.4 Investigation of the chelated diphosphine rhodium complex
5.5 Correlation of reaction selectivity and binding energy
5.6 Conclusions
References
Appendix A XP Spectra
反侵权盗版声明
封底
离子液体与光电子能谱（英文版）Ionicliquidsandphotoelectronspectro是2017年由电子工业出版社出版,作者 高景龙。
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